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Silver nanoparticles (Ag NPs) have promising plasmonic properties, however, they are rarely used in biomedical applications because of their potent toxicity. Herein, an electron compensation effect fr...
The quest for accurate exchange-correlation functionals has long remained a grand challenge in density functional theory (DFT), as it describes the many-electron quantum mechanical behavior through a ...
A novel chromophore composition of the bacterial photosynthetic reaction center (RC) has been discovered: RCs lacking the L-side monomeric bacteriochlorophyll chromophore result from mutation of the n...
Subpicosecond time-resolved absorption measurements at 77 K on two reaction center (RC) mutants of Rhodobacter capsulatus are reported. In the D(LL) mutant the D helix of the M subunit has been substi...
Stark spectra have been obtained in the region of absorption by the accessory bacteriochlorophylls (the B-band region around 800 nm) in Rhodobacter sphaeroides reaction centers. The Stark spectra in t...
Resonance Stark effects are nonclassical Stark effects associated with excited-state charge-transfer processes. The theory of resonance Stark effects developed in Part 2 of this series is generalized ...
A theory of the resonance Stark effect data reported in part 1 (preceding paper in this issue) is developed. The model used involves a weak charge resonance interaction between the excited state of an...
Higher order Stark spectroscopy has recently been introduced and applied to characterize the electrooptic properties of chromophores in bacterial photosynthetic reaction centers.1 In the course of the...
The quantum yield of the initial charge separation steps in bacterial photosynthetic reaction centers has been shown to be reduced in an applied electric field [Part I, Lao et al., J. Phys. Chem. 97 (...
The rates of electron-transfer reactions can be systematically varied by application of external electric fields. The electric field effect on the charge recombination rate constant of the state P[sup...
Extremely long distance electron transfer is observed in some photosynthetic reaction centers. For several charge recombination reactions, the rate appears to fall off much more slowly with distance t...
Electron-transfer reactions are expected to be particularly sensitive to externally applied electric fields because of the presence of charge-separated, dipolar states, and the effects of the field on...
The effect of an applied electric field on the kinetics of the initial picosecond electron-transfer reaction in Rb. sphaeroides reaction centers has been measured in isotropic samples at 77 K. The net...
A general method is demonstrated for experimentally obtaining the rate constant of electron transfer as a function of the free energy of the reaction in nonoriented systems. An external electric field...
The fluorescence intensity from randomly oriented, immobilized Rb. sphaeroides reaction centers at 77 K increases in the presence of an externally applied electric field. We have proposed that this in...

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