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青岛大气中HNO3、HNO2、NH3及PM2.5中氮组分的浓度特征和气-粒平衡关系
硝酸气体 亚硝酸气体 氨气
2014/12/20
研究PM2.5中NO3-、NO2-、NH4+及其气态前体物HNO3、HNO2、NH3的浓度特征和气-粒平衡关系,对深入认识PM2.5的来源及控制因素具有重要意义.因此,本文利用2012年6—7月在青岛采集的denuder和PM2.5大气样品,分析了其中气态和颗粒态氮组分的浓度.结果发现,青岛大气中HNO3、HNO2和NH3浓度分别为(0.80±0.79) μg·m-3、(0.49±0.59) μg...
Observations of NOx, $§igma$PNs, $§igma$ANs, and HNO3 at a Rural Site in the California Sierra Nevada Mountains: summertime diurnal cycles
NOx HNO3 California Sierra Nevada Mountains summertime diurnal cycles
2009/7/23
Observations of NO, NO2, total peroxy nitrates (ΣPNs), total alkyl nitrates (ΣANs), HNO3, CO, O3, and meteorological parameters were obtained from October 2000 through February 2002 at 1315 m a.s.l., ...
Uptake of HNO3 to deliquescent sea-salt particles: a study using the short-lived radioactive isotope tracer 13N
HNO3 deliquescent sea-salt particles short-lived radioactive isotope tracer 13N
2009/3/12
The uptake of HNO3 to deliquescent airborne sea-salt particles (RH = 55%, P = 760 torr, T = 300 K) at concentrations from 2 to 575 ppbv is measured in an aerosol flow tube using 13N as a tracer. Small...
Atmospheric measurements of gas-phase HNO3 and SO2 using chemical ionization mass spectrometry during the MINATROC field campaign 2000 on Monte Cimone
Atmospheric measurements gas-phase HNO3 chemical ionization mass spectrometry MINATROC field Monte Cimone
2009/3/10
The EU-project MINATROC (MINeral dust And TROpospheric Chemistry) aims at enabling an estimation of the influence of mineral dust, a major, but to date largely ignored component of tropospheric aeroso...
Gas-particle interactions above a Dutch heathland: III. Modelling the influence of the NH3-HNO3-NH4NO3 equilibrium on size-segregated particle fluxes
Gas-particle interactions Dutch heathland NH3-HNO3-NH4NO3 equilibrium particle fluxes
2009/3/2
Micrometeorological measurements of size-segregated particle number fluxes above Dutch heathlands and forests have repeatedly shown simultaneous apparent emission of particles with a diameter (Dp)<0.1...
Gas-particle interactions above a Dutch heathland：I. Surface exchange fluxes of NH3, SO2, HNO3 and HCl
Gas-particle interactions Dutch heathland NH3 SO2 HNO3
2009/2/27
A field measurement campaign was carried out over a Dutch heathland to investigate the effect of gas-to-particle conversion and ammonium aerosol evaporation on surface/atmosphere fluxes of ammonia and...
Growth of upper tropospheric aerosols due to uptake of HNO3
upper tropospheric aerosols HNO3
2009/2/24
The effect of nitric acid on the equilibrium size distributions of upper tropospheric aerosols is calculated as a function of relative humidity. It is shown that HNO3 concentrations above a few tenths...
Heterogeneous conversion of NO2 and NO on HNO3 treated soot surfaces: atmospheric implications
NO2 NO HNO3 soot surfaces atmospheric implications
2009/1/23
For the treatment of soot by pure HNO3 only reversible uptake with a surface coverage of ~1-2x1014 HNO3 cm-2 was observed for HNO3 mixing ratios in the range 250-800ppbv. Only for higher HNO3 mixing r...
MIPAS database: Validation of HNO3 line parameters using MIPAS satellite measurements
MIPAS database HNO3 line parameters MIPAS satellite measurements
2009/1/16
Using new and accurate experimental results concerning the spectroscopic properties of the HNO3 molecule as well as improved theoretical methods it has been possible to generate an improved set of lin...
On the ability of chemical transport models to simulate the vertical structure of the N2O, NO2 and HNO3 species in the mid-latitude stratosphere
chemical transport models vertical structure N2O HNO3 species mid-latitude stratosphere
2009/1/7
In this paper we study the impact of the modelling of N2O on the simulation of NO2 and HNO3 by comparing in situ vertical profiles measured at mid-latitudes with the results of the Reprobus 3-D CTM (T...
Balloon-borne radiometer measurements of Northern Hemisphere mid-latitude stratospheric HNO3 profiles spanning 12 years
Balloon-borne radiometer measurements Northern Hemisphere mid-latitude stratospheric HNO3
2008/12/26
Low-resolution atmospheric thermal emission spectra collected by balloon-borne radiometers over the time span of 1990–2002 are used to retrieve vertical profiles of HNO3, CFC-11 and CFC-12 volume mix...
Nitric acid (HNO3) is one of the key products that are operationally retrieved by the European Space Agency (ESA) from the emission spectra measured by the Michelson Interferometer for Passive Atmosp...
Comparisons between ground-based FTIR and MIPAS N2O and HNO3 profiles before and after assimilation in BASCOE
ground-based FTIR MIPAS N2O HNO3 BASCOE
2008/11/28
Within the framework of the Network for Detection of Atmospheric Composition Change (NDACC), regular ground-based Fourier transform infrared (FTIR) measurements of many species are performed at severa...
Impact of the new HNO3-forming channel of the HO2+NO reaction on tropospheric HNO3, NOx, HOx and ozone
HNO3-forming channel HO2+NO reaction tropospheric HNO3 NOx HOx ozone
2008/11/13
We have studied the impact of the recently observed reaction NO+HO2→HNO3 on atmospheric chemistry. A pressure and temperature-dependent parameterisation of this minor channel of the NO+HO2→NO2+OH reac...
Observations of HNO3, ΣAN, ΣPN and NO2 fluxes: evidence for rapid HOx chemistry within a pine forest canopy
HNO3 HOx chemistry forest canopy
2008/11/13
Measurements of exchange of reactive nitrogen oxides between the atmosphere and a ponderosa pine forest in the Sierra Nevada Mountains are reported. During winter, we observe upward fluxes of NO2, and...