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A novel chromophore composition of the bacterial photosynthetic reaction center (RC) has been discovered: RCs lacking the L-side monomeric bacteriochlorophyll chromophore result from mutation of the n...
The Stark spectrum of the intervalence band of the special pair radical cation in bacterial photosynthetic reaction centers is presented. This spectrum, centered at 2600 cm-1, is modeled using a gener...
The magnitudes of inter-chromophore interactions in bacterial photosynthetic reaction centers are investigated by measuring absorption and Stark spectra of reaction centers in which monomeric chromoph...
The electronic absorption spectrum of the homodimeric special pair in bacterial photosynthetic reaction centers is greatly modified when one of the bacteriochlorophylls is replaced by a bacteriopheoph...
Resonance Raman spectra and absolute Raman scattering intensities of the Franck-Condon coupled vibrational modes of the accessory bacteriochloropyhlls (B) in the photosynthetic reaction center from Rb...
The quantum yield of the initial charge separation steps in bacterial photosynthetic reaction centers has been shown to be reduced in an applied electric field [Part I, Lao et al., J. Phys. Chem. 97 (...
Rapid-flow resonance Raman vibrational spectra of bacterial photosynthetic reaction centers from the R-26 mutant of Rhodobacter sphaeroides have been obtained by using excitation wavelengths (810-910 ...
The effect of an applied electric field on the kinetics of the initial picosecond electron-transfer reaction in Rb. sphaeroides reaction centers has been measured in isotropic samples at 77 K. The net...
The fluorescence intensity from randomly oriented, immobilized Rb. sphaeroides reaction centers at 77 K increases in the presence of an externally applied electric field. We have proposed that this in...
Large hydrogen-isotopic (D/H) fractionations between lipids and growth water have been observed in most organisms studied to date. These fractionations are generally attributed to isotope effects i...
Natural remediation of oil spills is catalyzed by complex microbial consortia. Here we took a wholecommunity approach to investigate bacterial incorporation of petroleum hydrocarbons from a simulated ...

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