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系列Cu(Ⅱ/Ⅰ)配合物的制备及其表面光电压
Cu(Ⅱ)/Cu(Ⅰ) 晶体结构 表面光电压谱 场诱导表面光电压谱 电子跃迁
2009/11/17
采用水热法合成了{[Cu(phen)(H2O)(o-tpha)]·H2O}n(1), [Cu2Cl4(phen)2](2), [Cu4Cl4·(bipy)2](3)和[Cu2Cl2(phen)]n(4)(bipy=2,2'-bipyridyl, phen=1,10-phenanthroline, o-H2tpha=o-phthalic acid)4个铜配合物. X射线单晶衍射结果表明, 配合物1和...
The Synthesis of 4-Phenoxyphenylglyoxime and 4,4'-Oxybis(phenylglyoxime) and Their Complexes with Cu(II), Ni(II) and Co(II)
Keto oxime Glyoxime Transition metal complexes
2010/4/19
4-Acetyldiphenyl ether and 4,4'-diacetyldiphenyl ether were synthesized from diphenyl ether and acetyl chloride in the presence of AlCl3 used as catalyst. Subsequently, their keto oxime and glyoxime d...