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Unseen in the air around us are tiny molecules that drive the chemical cocktail of our atmosphere. As plants, animals, volcanoes, wildfires and human activities spew particles into the atmosphere, som...
Phase partitioning of NHx (gaseous NH3 and particulate NH4 +) in the atmosphere is crucial for the lifetime of NHx during atmospheric transport. Reliable data for gaseous NH3 and NH4 + in aerosols ...
In a companion paper, we introduced the Chemistry of Atmosphere-Forest Exchange (CAFE) model, a vertically-resolved 1-D chemical transport model designed to probe the details of near-surface reactive ...
Recent atmospheric measurements show that biological particles are a potentially important class of ice nuclei. Types of biological particles that may be good ice nuclei include bacteria, pollen and f...
We present the Chemistry of Atmosphere-Forest Exchange (CAFE) model, a vertically-resolved 1-D chemical transport model designed to probe the details of near-surface reactive gas exchange. CAFE integr...
Current deposition schemes used in atmospheric chemical transport models do not generally account for bi-directional exchange of ammonia (NH3). Bi-directional exchange schemes, which have so far been ...
We used a Single Column Chemistry and Transport Model (SCM) to infer the urban pollution emission fluxes of Manaus City, implying observed mixing ratios of CO, NOx and VOC. The model can reproduce the...
In the first part of this study for revisiting the cold condensation effect on global distribution of semi-volatile organic chemicals (SVOCs), the atmospheric transport of SVOCs to the Arctic in the m...
A box model using measurements from the Mexico City Metropolitan Area study in the spring of 2003 (MCMA-2003) is presented to study oxidative capacity (our ability to predict OH radicals) and ROx (ROx...
A detailed analysis of OH, HO2 and RO2 radical sources is presented for the near field photochemical regime inside the Mexico City Metropolitan Area (MCMA). During spring of 2003 (MCMA-2003 field camp...
We report the first measurements of 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea), a substitute for ozone depleting compounds, in air samples originating from remote regions of the atmosphere and prese...
We present atmospheric baseline growth rates from the 1970s to the present for the long-lived, strongly infrared-absorbing perfluorocarbons (PFCs) tetrafluoromethane (CF4), hexafluoroethane (C2F6), an...
Peroxyacetic acid (PAA) is one of the most important atmospheric organic peroxides, which have received increasing attention for their potential contribution to the oxidation capacity of the troposphe...
Very short-lived halocarbons are significant sources of reactive halogen in the marine boundary layer, and likely in the upper troposphere and lower stratosphere. Quantifying ambient concentrations in...
Bacteria are ubiquitous in the atmosphere, with concentrations of bacterial cells typically exceeding 1×104 m−3 over land. Numerous studies have suggested that the presence of bacteria in the at...

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