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2017年无机反应机理高登研究研讨会(The Gordon Research Seminar in Inorganic Reaction Mechanisms)
2017年 无机反应机理高登研究 研讨会
2017/2/13
The Gordon Research Seminar on Inorganic Reaction Mechanisms is a unique forum for graduate students, post-docs, and other scientists with comparable levels of experience and education to present and ...
2017年无机反应机理戈登学术会议(The Gordon Research Conference (GRC) on Inorganic Reaction Mechanisms)
Inorganic Reaction Mechanisms synthetic chemistry
2017/1/18
Understanding the mechanism of a chemical reaction is essential for controlling selectivity and yield of products, and improving the efficiency of chemical processes. The principles of inorganic mecha...
Solvation Response Along the Reaction Coordinate in the Active Site of Ketosteroid Isomerase
Pseudomonas putida Coumarins Isomerases Spectrometry, Fluorescence Catalytic Domain Ketosteroids Biocatalysis Light Models, Molecular Equilenin
2016/5/25
A light-activated reaction analog has been developed to mimic the catalytic reaction cycle of Delta(5)-3-ketosteroid isomerase to probe the functionally relevant protein solvation response to the cata...
High Yield of M-Side Electron Transfer in Mutants of Rhodobacter Capsulatus Reaction Centers Lacking the L-Side Bacteriopheophytin
Rhodobacter capsulatus Pheophytins Detergents Spectrum Analysis Oxidation-Reduction Mutation Plasmids Amino Acid Sequence Molecular Sequence Data Histidine
2016/5/24
We present studies on a series of photosynthetic reaction center (RC) mutants created in the background of the Rhodobacter capsulatus D(LL) mutant, in which the D helix of the M subunit has been subst...
Energetics of Primary Charge Separation in Bacterial Photosynthetic Reaction Center Mutants:Triplet Decay in Large Magnetic Fields
horseradish peroxidase lignin peroxidase enzymatic oxidations N-demethylation methylene blue azure B azure C
2016/5/24
The triplet state of aromatic molecules forms and decays by intersystem crossing, as originally demonstrated by Kasha and Lewis. By contrast, the triplet state of the primary electron donor, 3 P, in p...
Excited State Energy Transfer Pathways in Photosynthetic Reaction Centers.4.Asymmetric Energy Transfer in the Heterodimer Mutant
in-modified beta zeolite reductive solid-state ion exchange Lewis acidity m-xylene transformation
2016/5/23
In bacterial photosynthetic reaction centers, ultrafast singlet excited state energy transfer occurs from the monomeric bacteriochlorophylls, B, and bacteriopheophytins, H, to the homodimer special pa...
The Mechanism of Triplet Energy Transfer from the Special Pair to the Carotenoid in Bacterial Reaction Centers
Triplet Energy Transfer Carotenoid Bacterial Reaction Centers
2016/5/23
The kinetics of triplet energy transfer from the primary electron donor P, a bacteriochlorophyll dimer, to the carotenoid were measured in the M182HL mutant of Rhodobacter sphaeroides photosynthetic r...
Excited State Electronic Asymmetry of the Special Pair in Photosynthetic Reaction Center Mutants:Absorption and Stark Spectroscopy
Dimerization Electron Transport Electrons Hydrogen Bonding Models, Chemical Mutagenesis, Site-Directed Oxidation-Reduction Photosynthetic Reaction Center Complex Proteins Rhodobacter sphaeroides Spectrophotometry Static Electricity
2016/5/23
The electronic absorption line shape and Stark spectrum of the lowest energy Q(y)() transition of the special pair in bacterial reaction centers contain a wealth of information on mixing with charge t...
Temperature Dependece of the Qy Resonance Raman Spectra of Bacteriochlorophylls,the Primary Electron Donor,and Bacteriopheophytins in the Bacterial Photosynthetic Reaction Center
Bacteriochlorophylls chemistry Electron Transport Infrared Rays Light-Harvesting Protein Complexes Pheophytins chemistry Photosynthetic Reaction Center Complex Proteins chemistry Research Support, U.S. Gov't, Non-P.H.S. Research Support,U.S. Gov't,P.H.S. Rhodobacter sphaeroides chemistry Spectrophotometry
2016/5/23
Qy-excited resonance Raman spectra of the accessory bacteriochlorophylls (B), the bacteriopheophytins (H), and the primary electron donor (P) in the bacterial photosynthetic reaction center (RC) of Rh...
Architecture and Function of Membrane Proteins in Planar Supported Bilayers:A Study with Photosynthetic Reaction Centers
Arabidopsis plant DNA repair photoreactivation plant blue-light receptor AT-PHH1
2016/5/23
We present a simple and convenient method for creating fluid supported bilayers which contain oriented and functional photosynthetic reaction centers (RCs). The supported bilayers are prepared by fusi...
Rapid Isolation of Bacterial Photosynthetic Reaction Centers with an Engineered Poly-Histidine Tag
photosynthetic reaction center poly-histidine tag isolation method (bacterium)
2016/5/23
A very rapid method for isolating bacterial photosynthetic reaction centers (RCs) of high purity and yield is described. A poly-histidine tag is engineered at the C-terminus of the RC M-subunit, allow...
Excited State Energy Transfer Pathways in Photosynthetic Reaction Centers.1.Structural Symmetry Effects
biology and medicine,basic studies chemistry solar energy photosynthetic reaction centers energy transfer temperature dependence chemical reaction kinetics excited states molecular structure symmetry
2016/5/23
Ultrafast excited state energy transfer to the primary electron donor or special pair in photosynthetic reaction centers has been measured following excitation of the lowest electronic state of the ot...
Mg Coordination by Amino Acid Side Chains is Not Required for Assembly and Function of the Special Pair in Bacterial Photosynthetic Reaction Centers
Amino Acids Fourier Analysis Light-Harvesting Protein Complexes Magnesium xidation-Reduction Photosynthetic Reaction Center Complex Proteins Spectrometry,Fluorescence Spectrum Analysis, Raman
2016/5/23
A conserved histidine serves as the axial ligand to the Mg of bacteriochlorophylls in the photosynthetic reaction center (RC) and many other photosynthetic systems. The histidine axial ligands to each...
Stark Effect (Electroabsorption) Spectroscopy of Photosynthetic Reaction Centers at 1.5 K:Evidence that the Special Pair has a Large Excited-State Polarizability
Photosynthesis Reaction center Stark spectroscopy Specialpair
2016/5/23
The Stark effect or electroabsorption spectrum of the Qy transition of the special pair, P, of Rb. sphaeroides reaction centers has been measured at 1.5 K in frozen glycerol/buffer glasses. Under thes...
Photosynthetic Reaction Center Mutagenesis via Chimeric Rescue of a Non-functional Rhodobacter capsulatus puf Operon with Sequences from Rhodobacter sphaeroides
photosynthesis recombination bacteria energy transfer antenna
2016/5/23
Photosynthetically active chimeric reaction centers which utilize genetic information from both Rhodobacter capsulatus and Rb. sphaeroides puf operons were isolated using a novel method termed chimeri...